By Bessaih H., Flandoli F.
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Extra info for 2-D Euler equation perturbed by noise
J. Polym. Sei. Polym. Chem. Copyright 0 1981 John Wiley & Sons, Inc. Reprinted Ed, 19, 3173 (1981). by permission of John Wiley & Sons, Inc. 78 In(kt)=12. 60, - k,: termination rate constant, [dm3/mol sec] a,: weight fraction of polymer, [-I Ballard, M. , Napper, D. , and Gilbert, R. , J. Polym. Sei. Polym. Chem. , 22, 3225 (1984). Copyright 0 1984 John Wiley & Sons, Inc. Reprinted by permission of John Wiley & Sons, Inc. 33 S 0 ~ 5 0 . 84 5 0 ~ 5 0 . 9 9 ) fraction of polymer, [-I k,: propagation rate constant, [dm3/mol * sec] kpo: propagation rate constant in the absence of diffusion, [dm3/mol-sec] 0,:weight Ballard, M.
London, A197, 356 ( 1949). Photo-induced bulk polymerization Sensitizer: biacetyl Temperature: 5-70 “C Initiation Propagation Transfer with monomer Termination S + hv 2R* R. + M M. + M M,. + M Me + Me --+ 2R. -+s -+ --j + + M. l 2ka[R. I [MI k,[M * 1[MI ktr[Mr. : polymer radical containing r units of monomer, M,: dead polymer containing r units of monomer.
93. sec] k,: initiation rate constant, [I/mol*sec] kPr: propagation rate constant of polymer radical containing r units, [I/mol*sec] k,: termination rate constant, [I/mol. , Makromol. , 111, 115 (1968). 32/mol' 32 sec] k,": chain transfer rate constant to monomer, [I/mol*sec] kK: chain transfer rate constant to initiator, [I/mol. sec] k,: propagation rate constant, [I/mol*sec] - Imoto, M. , Makromol. , 117, 117 (1968). OX 10'5exp(-29100 cal/RT) for 50-80°C [i]: concentration of species i, [mol/l] R,: initial rate of polymerization, [mol/l.